Hydrogenation of α,β-Unsaturated Aldehydes and Ketones to the Unsaturated Alcohols catalysed by Hydridoiridium Phosphine Complexes

DOI: 10.1039/c39860000746

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 746 - 747 (1986)

Update date:2022-08-10

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Authors:

Farnetti, E.

Pesce, M.

Kaspar, J.

Spogliarich, R.

Graziani, M.

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Article abstract of DOI:10.1039/c39860000746

Unusual selective hydrogenation of cinnamaldehyde and benzylideneacetone to the corresponding unsaturated alcohols is catalysed by (+) complexes in toluene; use of a chiral phosphine gives a 7.4percent enantiomeric excess of (S)-(-)-1-phenylbut-1-en-3-ol.

Full text of DOI:10.1039/c39860000746

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