"Counter" Phase Transfer Catalysis by Water-soluble Phosphine Complexes. Catalytic Reduction of Allyl Chlorides and Acetates with Sodium Formate in Two-phase Systems

DOI: 10.1246/cl.1986.1463

Source and publish data:

Chemistry Letters p. 1463 - 1466 (1986)

Update date:2022-08-11

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Authors:

Okano, Tamon

Moriyama, Yoshiyuki

Konishi, Hisatoshi

Kiji, Jitsuo

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Article abstract of DOI:10.1246/cl.1986.1463

In the reduction of allyl chlorides and acetates with sodium formate in a heptane-water two-phase system, water-soluble palladium complexes function as a novel type of catalyst which transports the substrate into the aqueous phase and causes it to react with sodium formate.

Full text of DOI:10.1246/cl.1986.1463

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