Tetrahedron Letters p. 5157 - 5160 (1981)
Update date:2022-08-11
Topics:
Mueller, Paul
Bobillier, Christiane
Oxidation of anthracene to anthraquinone by oxygen/RhCl(PPh3)3 proceeds via solvent derived hydroperoxydes. tert-Butylhydroperoxide/RhCl(PPh3)3 effects the same transformation in up to 96percent yield.Possible mechanisms for the TBHP-catalyzed reaction are discussed.
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