1,2-Bond Shift Isomerization of Oxiranes on Copper-Graphimet

DOI: 10.1039/c39890000124

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 124 - 126 (1989)

Update date:2022-08-17

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Authors:

Molnar, Arpad

Mastalir, Agnes

Bartok, Mihaly

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Article abstract of DOI:10.1039/c39890000124

2,2,3,3-Tetramethyloxirane (1) undergoes isomerization on copper intercatated graphite (graphimet) to t-butyl methyl ketone (4) via a 1,2-methyl migration and to 2,3-dimethylbut-3-en-2-ol (5) via a 1,3-hydrogen shift, as well as deoxygenation and dehydration products.

Full text of DOI:10.1039/c39890000124

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