Preliminary communication. Kinetic spectroscopy of diphenylgermylene Ph2Ge following laser flash photolysis of bis(trimethylsilyl)diphenylgermane (Me3Si)2GePh2

DOI: 10.1016/0022-328X(88)89115-0

Source and publish data:

Journal of Organometallic Chemistry p. C17 - C22 (1988)

Update date:2022-08-30

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Authors:

Konieczny, Stanislaw

Jacobs, S. Joshua

Wilking, Janet K. Braddock

Gaspar, Peter Paul

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Article abstract of DOI:10.1016/0022-328X(88)89115-0

A transient, λ_max 445 nm, was observed in the 266 nm laser flash photolysis of cyclohexane solutions of (Me3Si)2GePh2, and rate constants were recorded for its disappearance in the presence of various trapping agents.The reactivity profile is in accord with the identification of the carrier as diphenylgermylene Ph2Ge, that dimerizes to tetraphenyldigermene Ph2Ge=GePh2, λ7max3 320 nm.

Full text of DOI:10.1016/0022-328X(88)89115-0

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