Tetrahedron Letters p. 7659 - 7660 (1996)
Update date:2022-08-11
Topics:
Harrowven, David C.
Dainty, Richard F.
Zirconium tetrachloride has been found to be an excellent mediator of the Fries reaction. Rearrangements occur at ambient temperature and are highly selective; giving the acetophenone derived from acetyl migration to the sterically least encumbered adjacent carbon.
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