THE ANOMERIC EFFECT IN 2-ARYLSELENO-1,3-DITHIANES

DOI: 10.1016/S0040-4039(00)95003-2

Source and publish data:

Tetrahedron Letters p. 5235 - 5238 (1985)

Update date:2022-08-16

Topics:

Authors:

Pinto, B. Mario

Sandoval-Ramirez, Jesus

Sharma, R. Dev

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Article abstract of DOI:10.1016/S0040-4039(00)95003-2

The anomeric effect in a series of 2-(4-substituted-phenylseleno)-1,3-dithianes (substituens, R = NO2, CF3, H, OMe, NMe2) decreases in the sequence NO2>CF3>H>OMe>NMe2, providing systematic experimental evidence for the role of stabilizing orbital interactions.

Full text of DOI:10.1016/S0040-4039(00)95003-2

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