Journal of the Chemical Society. Chemical communications p. 1749 - 1751 (1989)
Update date:2022-08-16
Topics:
Ogawa, Takuji
Murafuji, Toshihiro
Suzuki, Hitomi
Bismuthonium ylides are generated by reacting triphenylbismuth oxide or dichloride with sodium salts of cyclic and open chain 1,3-dicarbonyl compounds; ylides from open chain 1,3-dicarbonyl compounds, which readily decompose on standing to produce C-phenylation products, can be efficiently trapped by sulphenes to afford 1,3-oxathiole-3,3-dioxides in good yields.
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