DIVALENT SAMARIUM-INDUCED CYCLOPROPANATION OF LITHIUM ENOLATES. A ONE-POT SYNTHESIS OF CYCLOPROPANOLS FROM KETONES

DOI: 10.1016/S0040-4039(00)95354-1

Source and publish data:

Tetrahedron Letters p. 1307 - 1308 (1987)

Update date:2022-08-03

Topics:

Authors:

Imamoto, Tsuneo

Takiyama, Nobuyuki

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Article abstract of DOI:10.1016/S0040-4039(00)95354-1

Lithium enolates, generated by deprotonation of ketones with lithium diisopropylamide, react with diiodomethane in the presence of SmI2 to give cyclopropanols.

Full text of DOI:10.1016/S0040-4039(00)95354-1

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