Mono-hydrofluorination of Electrophilic Alkynes by the Liquid Bishasic CsF-H2O-DMF System (DMF = N,N-dimethylformamide)

DOI: 10.1039/c39890001493

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1493 - 1494 (1989)

Update date:2022-08-30

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Authors:

Gorgues, Alain

Stephan, Dominique

Cousseau, Jack

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Article abstract of DOI:10.1039/c39890001493

CsF induces the addition of HF in fair yields to activated acetylenic triple bonds in a DMF-water bishasic medium (DMF = N,N-dimethylformamide); in a homogeneous DMF-water mixture, no addition is observed.

Full text of DOI:10.1039/c39890001493

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