Co(II)-salen-catalyzed highly cis- and enantioselective cyclopropanation

DOI: 10.1016/S0040-4039(00)00433-0

Source and publish data:

Tetrahedron Letters p. 3647 - 3651 (2000)

Update date:2022-08-17

Topics:

Authors:

Niimi, Tatsuo

Uchida, Tatsuya

Irie, Ryo

Katsuki, Tsutomu

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Article abstract of DOI:10.1016/S0040-4039(00)00433-0

The reactions of styrene derivatives and t-butyl α-diazoacetate using (R,R)-(salen)cobalt(II) complex 6 as a catalyst in the presence of N- methylimidazole gave the corresponding cyclopropanecarboxylates with excellent enantio- (>95% ee) and high cis-ster

Full text of DOI:10.1016/S0040-4039(00)00433-0

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