New hemiterpenoid pentol and monoterpenoid glycoside of Torillis japonica fruit, and consideration of the origin of apiose

DOI: 10.1248/cpb.46.1583

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1583 - 1586 (1998)

Update date:2022-08-11

Topics:

Authors:

Kitajima, Junichi

Suzuki, Nobuyuki

Ishikawa, Toru

Tanaka, Yasuko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.46.1583

From the water-soluble portion of Torillis japonica D.C. fruit, a new hemiterpenoid pentol, (3R)-2-hydroxymethylbutane-1,2,3,4-tetrol (1) and a new monoterpenoid apiosyl-glucoside (4) have been isolated together with known (2S,3R)-2-methylbutane-1,2,3,4-tetrol (2) and hemiterpenoid glucoside (3). As 2 is a commonly existing constituent in Umbelliferous plants, and considered to be the first putative precursor of isoprenoid derived from glucose, we assumed that apiose and these hemiterpenoids may be biosynthesized from glucose by a mevalonate-independent route of isoprenoid.

Full text of DOI:10.1248/cpb.46.1583

NII-Electronic Library Service

Products guided by the article

Product name:3-(hydroxymethyl)erythritol

Cas No:10592-17-3

R&D Labs maybe for 10592-17-3

Puyang Willing Chemicals Co.,Ltd.

Contact:86-393-4840366

Address:Puyang Henan China
Xuzhou Tianrun Chemical Co.,Ltd

website:http://www.tianrunchem.cn

Contact:86-516-83832636

Address:fuxing road
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Jiangxi Global Natural Spice Co., Ltd.

website:https://www.jxhqxl.com/

Contact:+86-796-8106598

Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
JADECHEM NINGBO CO.,LTD.

Contact:+86-574-89075960

Address:#100 Xiang Yun Road, New High tech area, Ningbo, China

Relevant to this article

N-H insertion reactions of rhodium carbenoids. Part 1. Preparation of α-amino acid and α-aminophosphonic acid derivatives

Doi:10.1039/P19960002879
(1996)
Novel synthetic approach, spectroscopic characterization and theoretical studies on global and local reactive properties of a bibenzimidazolyl derivative

Doi:10.1016/j.molstruc.2017.06.073
(2017)
Preparation of C₉-aldehyde via aldol condensation reactions in ionic liquid media

Doi:10.1039/b203068c
(2002)
Linkage effects on binding affinity and activation of GPR30 and estrogen receptors ERα/β with tridentate pyridin-2-yl hydrazine tricarbonyl-Re/^99mTc(I) chelates

Doi:10.1021/ja066360p
(2006)
A BRIDGEHEAD α-AMINO CARBANION: FACILE PREPARATION OF C5(BRIDGEHEAD)-SUBSTITUTED ANALOGUES OF (+/-)-5H-DIBENZOCYCLOHEPTEN-5,10-IMINE INCLUDING A STABLE α-IODO SECONDARY AMINE

Doi:10.1016/S0040-4039(00)95276-6
(1989)
Doi:10.1021/je60048a033
(1971)

Article Doi