New hemiterpenoid pentol and monoterpenoid glycoside of Torillis japonica fruit, and consideration of the origin of apiose

DOI: 10.1248/cpb.46.1583

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1583 - 1586 (1998)

Update date:2022-08-11

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Authors:

Kitajima, Junichi

Suzuki, Nobuyuki

Ishikawa, Toru

Tanaka, Yasuko

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Article abstract of DOI:10.1248/cpb.46.1583

From the water-soluble portion of Torillis japonica D.C. fruit, a new hemiterpenoid pentol, (3R)-2-hydroxymethylbutane-1,2,3,4-tetrol (1) and a new monoterpenoid apiosyl-glucoside (4) have been isolated together with known (2S,3R)-2-methylbutane-1,2,3,4-tetrol (2) and hemiterpenoid glucoside (3). As 2 is a commonly existing constituent in Umbelliferous plants, and considered to be the first putative precursor of isoprenoid derived from glucose, we assumed that apiose and these hemiterpenoids may be biosynthesized from glucose by a mevalonate-independent route of isoprenoid.

Full text of DOI:10.1248/cpb.46.1583

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