Chemical and Pharmaceutical Bulletin p. 1583 - 1586 (1998)
Update date:2022-08-11
Topics:
Kitajima, Junichi
Suzuki, Nobuyuki
Ishikawa, Toru
Tanaka, Yasuko
From the water-soluble portion of Torillis japonica D.C. fruit, a new hemiterpenoid pentol, (3R)-2-hydroxymethylbutane-1,2,3,4-tetrol (1) and a new monoterpenoid apiosyl-glucoside (4) have been isolated together with known (2S,3R)-2-methylbutane-1,2,3,4-tetrol (2) and hemiterpenoid glucoside (3). As 2 is a commonly existing constituent in Umbelliferous plants, and considered to be the first putative precursor of isoprenoid derived from glucose, we assumed that apiose and these hemiterpenoids may be biosynthesized from glucose by a mevalonate-independent route of isoprenoid.
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