Journal of the Chemical Society. Chemical communications p. 421 - 423 (1989)
Update date:2022-08-18
Topics:
Bressan, Mario
Morvillo, Antonino
Selective hydroxylation (or ketonization) of cyclic alkanes and conversion of ethers to esters and of secondary alcohols to ketones, with significant rates (up to ca. 1 turnover per minute at room temperature), were achieved by using hypochlorite as oxidant and a choice of ruthenium(II) complexes as catalysts, in a biphastic water-dichloromethane system.
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