Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 339 - 348 (1986)
Update date:2022-08-11
Topics:
Opallo, Marcin
The one-electron electro-oxidation of 1,4-phenylenediamine to the corresponding radical cation has been studied by cyclic voltammetry at a Pt electrode in perchlorate solutions in a wide range of aprotic and hydrogenbonded solvents.A linear relationship between the redox potential of this system and the donor number of a given solvent has been found.It has been shown that the dynamics of solvent reorientation strongly affects the heterogeneous electron transfer rate in the studied case: an almost linear relationship between the standard rate constant and the reciprocal of the longitudinal dielectric relaxation time of a given solvent has been found.It has been suggested that the solvent dynamics affects the rate of the analogous homogeneous electron-transfer reaction.
View MoreJiangsu Glory Chemical Co., Ltd.
Contact:+86-571-87896791
Address:Yanhua Chemical Park, Hongze, Huai'an, Jiangsu, China
HEZE KINGVOLT CHEMICAL CO., LTD
Contact:86-573-82118911
Address:Juancheng Industry Park
Hangzhou Pharma & Chem Co.,Ltd.
Contact:+86-571-87040515
Address:No,139Qingchun Rd
Qingdao Kingway Pharmtech Co., Ltd.
Contact:86-532-87118899
Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China
Shijiazhuang Haitian Amino Acid Co., Ltd.
Contact:+86-311-88908111
Address:Shijiazhuang Hebei province,China
Doi:10.1055/s-2003-41017
(2003)Doi:10.1016/j.ica.2016.08.035
(2017)Doi:10.1016/j.bmc.2004.08.008
(2004)Doi:10.1021/ja00056a018
(1993)Doi:10.1002/hlca.193601901167
(1936)Doi:10.1080/00397919608003612
(1996)