Ruthenium-Catalyzed Isomerization of Allylic Alcohols to Saturated Ketones

DOI: 10.1016/S0040-4039(00)73934-7

Source and publish data:

Tetrahedron Letters p. 5459 - 5462 (1993)

Update date:2022-08-28

Topics:

Authors:

Baeckvall, Jan-E.

Andreasson, Ulrika

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Article abstract of DOI:10.1016/S0040-4039(00)73934-7

Highly efficient ruthenium-catalyzed isomerization of allylic alcohols to ketones have been developed.A dramatic rate enhancement by the presence of a catalytic amount of base was observed in the isomerization catalyzed by either RuCl2(PPh3) (3) or 2 (4).Dimetallic catalyst 5, which can itself serve as a base, led to a rapid reaction without the addition of extra base.

Full text of DOI:10.1016/S0040-4039(00)73934-7

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