Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 175 - 184 (1985)
Update date:2022-08-18
Topics:
Shimazu, Katsuaki
Kita, Hideaki
Deuteration of buta-1,3-diene on Al2O3-supported Pt, Pd, Rh and Ru catalysts in 0.5 mol dm-3 D2SO4 has been examined to see if there are differences in their catalytic action.The results are discussed on the basis of a simple common scheme in which butenes are formed via half-hydrogenated species and deuterium uptake proceeds by the reversible occurrence of two steps, namely (i) the formation of the half hydrogenated species and (ii) the ionization of adsorbed hydrogen
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