Journal of the Chemical Society. Chemical communications p. 1114 - 1115 (1981)
Update date:2022-08-11
Topics:
Okuhara, Toshio
Kobayashi, Kenji
Kimura, Tomoo
Misono, Makoto
Yoneda, Yukio
A highly dispersed Ru/Al2O3 catalyst, prepared from Ru3(CO)12 was much more active and selective for C2-C5 olefins in the hydrogenation of CO than conventionally prepared Ru/Al2O3 catalyst, and addition of K to the carbonyl-derived catalyst enhanced significantly the preferential formation of light olefins (ca. 80percent at 260 deg C).
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