Bulletin of the Chemical Society of Japan p. 3503 - 3504 (1983)
Update date:2022-08-11
Topics:
Akimoto, Masamichi
Sakatani, Takashi
Echigoya, Etsuro
Ethylene and propylene were produced at high yields, additionally to butenes and butadiene, by the vapor-phase oxidative dehydrogenation of butane with COS over SiO2, Al2O3, MgO, and TiO2 catalysts at 873-923K.The results of kinetic and mechanistic studies indicate that ethylene and propylene are produced by the oxidative dehydrogenation through a homolytic mechanism followed by β-scission of the carbon-carbon bond.
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