Synthetic Communications p. 675 - 681 (1991)
Update date:2022-08-23
Topics:
Adams
Press
Deegan
Literature methods to prepare 1 failed and a reaction sequence was developed to prepare 4-hydroxy-1H-indole-2-carbonitrile (1) by means of an azide decomposition to form the indole ring. The 2-cyano functionality could not be introduced directly but was derived by functionalization of an ester.
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Doi:10.1021/ja00428a032
(1976)Doi:10.1002/anie.200453729
(2004)Doi:10.1002/anie.201606722
(2016)Doi:10.1021/jo01306a014
(1980)Doi:10.1021/acs.orglett.1c00638
(2021)Doi:10.1002/cctc.201501292
(2016)