Alkoxyoxaziridines. Stereochemical Aspects of Imidate Oxidation, an Asymmetric Synthesis, and Unusually Facile E-Z Isomerizations

DOI: 10.1021/jo00367a004

Source and publish data:

Journal of Organic Chemistry p. 3266 - 3270 (1986)

Update date:2022-08-29

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Authors:

Gonzales,C. Orestes

Gallis, David E.

Crist, DeLanson R.

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Article abstract of DOI:10.1021/jo00367a004

The synthesis of new, mechanistically useful 3-methoxy-3-phenyloxaziridines was accomplished by oxidation of imidate esters with m-chloroperbenzoic acid.Unlike previously known imidates, methyl N-tert-butylbenzimidate undergoes rapid E-Z isomerization at

Full text of DOI:10.1021/jo00367a004

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