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Formation of an Epoxide Intermediate in the Photo-oxidation of Alkenes over Silica-supported Vanadium Oxide

DOI: 10.1039/f19868200035

Source and publish data:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 35 - 44 (1986)

Update date:2022-08-10

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Authors:

Tanaka, TsunehiroTanaka, Tsunehiro

Ooe, MasaharuOoe, Masaharu

Funabiki, TakuzoFunabiki, Takuzo

Yoshida, SatohiroYoshida, Satohiro

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Article abstract of DOI:10.1039/f19868200035

Photo-induced isomerization of propene oxide and photo-oxidation of ethene have shown that photo-oxidation of alkenes proceeds by a mechanism involving not only the oxidative cleavage of the olefinic double bond and oxidation via ?-allyl intermediates, but also the formation of epoxides as a precursor.The product distribution in the photo-oxidation of butenes is well explained by the mechanism.A tracer study using 18O2 has indicated that oxygen involved in the epoxide intermediate comes from the lattice oxygen of the catalyst.

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