Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 173 - 180 (1987)
Update date:2022-08-16
Topics:
Danen, Wayne C.
Setser, D. W.
Nguyen, Hanh H.
Ibrahim, Md. Sani B.
Several examples of synthetically unique reaction controll effect by pulsed infrared laser multiphoton irradiation are reviewed.The uniqueness derives from the ability of the pulsed laser to rapidly vibrationally heat molecules coupled with an extremely short reaction time of approximately 10 μs for the processes discussed herein.Three systems are discussed: a bifunctional reactant with competing reaction channels, a reactant with consecutive reaction channels, and the free radical chlorination of cyclopropane.
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