Journal of the Chemical Society. Chemical communications p. 1171 - 1173 (1986)
Update date:2022-08-29
Topics:
Rollins, Keith
Sermon, Paul A.
Temperature-programmed reduction of metal chlorides upon silica, alumina, and titania supports using ethene produces chloroethene and 1,2-dichloroethane, together with rather unexpectedly, 1,1-dichloroethane and benzene in yields which differ from one metal chloride to another; results suggest the involvement of novel ..H/Cl.. exchange and oxidative-coupling reactions and also suggest that this technique of ethene titration may be of value in characterising the active sites in chloride catalysts and catalytic precursors.
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