J Po lue ran sael od fo Mn aot te rai ad l js u Cs ht emm ai rs gt ri yn sA
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ARTICLE
Journal Name
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Lett., 2001, 344, 339-344.
2 K. S. Leschkies, R. Divakar, J. Basu, E. Enache-Pommer, J. E.
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Besides, holes in the VB of WO can also take part in the direct
aromatic alcohols oxidization to aldehydes.
DOI: 10.1039/D0TA07235D
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. Conclusions
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3 D. B. Ingram and S. Linic, J. Am. Chem. Soc., 2011, 133, 5202-
5
205.
In summary, Z-scheme artificial photosystem was elaborately
designed on the WO NRs with Pd NCs self-assembled on the
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4 J. S. DuChene, B. C. Sweeny, A. C. Johnston-Peck, D. Su, E.
A. Stach and W. D. Wei, Angew. Chem. Int. Ed. Engl., 2014,
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surface followed by uniform CdS encapsulation leading to WO
NRs@Pd@CdS core-shell heterostructure. The WO
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3, 7887-7891.
15 H. J. Chen, L. Shao, Q. Li and J. F. Wang, Chem. Soc. Rev.,
013, 42, 2679-2724.
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NRs@Pd@CdS heterostructure exhibits significantly enhanced
net efficiency of photoactivities toward selective reduction of
nitroaromatics to amino derivatives and selective oxidation of
aromatic alcohols to aldehydes with favorable photostability.
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6 L. J. Zhang, S. Li, B. K. Liu, D. J. Wang and T. F. Xie, ACS
Catal., 2014, 4, 3724-3729.
7 K.-Y. Jiang, X.-C. Dai, Y. Yu, Q.-L. Mo and F.-X. Xiao, J.
Phys. Chem. C, 2018, 122, 12291-12306.
1
The Pd NCs integrated in-between WO
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core and CdS shell 18 Y.-B. Li, T. Li, X.-C. Dai, M.-H. Huang, Y. He, G. Xiao and
F.-X. Xiao, J. Mater. Chem. A, 2019, 7, 8938-8951.
9 W. Xiang, Y. Zhao, Z. Jiang, X. Li, H. Zhang, Y. Sun, Z. Ning,
F. Du, P. Gao, J. Qian, K. Kato, M. Yamauchi and Y. Sun, J.
Mater. Chem. A, 2018, 6, 23366-23377.
0 Y. X. Pan, Y. You, S. Xin, Y. Li, G. Fu, Z. Cui, Y. L. Men, F.
F. Cao, S. H. Yu and J. B. Goodenough, J. Am. Chem. Soc.,
considerably accelerate the Z-scheme charge transfer, wherein
Pd NCs serve as high-efficiency Schottky-type electron transport
mediators, giving rise to the considerably improved charge
separation and greatly enhanced photoredox performances.
Dominant active species in-situ formed in the photoredox
organic transformation were identified with Z-scheme
photoredox mechanism clearly elucidated. Our work
demonstrates a promising and sustainable paradigm for smartly
designing Z-scheme photosystems for solar-to-chemical energy
conversion.
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017, 139, 4123-4129.
1 M.-H. Huang, Y.-B. Li, T. Li, X.-C. Dai, S. Hou, Y. He, G.
Xiao and F.-X. Xiao, Chem. Commun., 2019, 55, 10591-
1
0594.
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2 M.-H. Huang, X.-C. Dai, T. Li, Y.-B. Li, Y. He, G. Xiao and
F.-X. Xiao, J. Phys. Chem. C, 2019, 123, 9721-9734.
3 H.-J. Lin, T. Li, M.-H. Huang, X.-C. Dai, Y.-B. Li and F.-X.
Xiao, J. Phys. Chem. C, 2019, 123, 28066-28080.
4 24. P. Zhou, J. Yu and M. Jaroniec, Adv. Mater., 2014, 26,
Conflicts of interest
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920-4935.
There are no conflicts to declare.
25 Y. B. Li, T. Li, X. C. Dai, M. H. Huang, S. Hou, X. Y. Fu, Z.
Q. Wei, Y. He, G. Xiao and F. X. Xiao, ACS Appl Mater
Interfaces, 2020, 12, 4373-4384.
2
6 S. Xu, M.-H. Huang, T. Li, Z.-Q. Wei, X. Lin, X.-C. Dai, S.
Hou, X.-Y. Fu and F.-X. Xiao, J. Mater. Chem. A, 2020, 8,
8360-8375.
7 M. Seifollahi Bazarjani, M. Hojamberdiev, K. Morita, G. Zhu,
G. Cherkashinin, C. Fasel, T. Herrmann, H. Breitzke, A. Gurlo
and R. Riedel, J. Am. Chem. Soc., 2013, 135, 4467-4475.
8 Y. Xiao, T. Wang, G. Qiu, K. Zhang, C. Xue and B. Li, J.
Colloid Interface Sci., 2020, 577, 459-470.
9 Y. Xiao, X. Tao, G. Qiu, Z. Dai, P. Gao and B. Li, J. Colloid
Interface Sci., 2019, 550, 99-109.
0 R. Wang, G. Qiu, Y. Xiao, X. Tao, W. Peng and B. Li, J.
Catal., 2019, 374, 378-390.
Acknowledgements
The support by the award Program for Minjiang scholar
professorship is greatly acknowledged. This work was
financially supported by the National Natural Science
Foundation of China (Nos. 21703038).
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