Tetrahedron p. 1963 - 1974 (1990)
Update date:2022-08-17
Topics:
Agarwal, Seema
Tiwari
Sharma
Based on the experimental data, a definite mechanism for the oxidation of primary and secondary alcohols with PCC and two newly synthesized Cr(VI) reagents has been proposed. The reaction has been shown to be a series reaction rather than a simple one step reaction as reported in the literature. The mechanism proposed has been exemplified by taking 2-pentanol as an example. The kinetic isotope studies have also been performed.
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