A series second-first-order mechanism for the oxidation of primary and secondary alcohols by Cr(VI) reagents

DOI: 10.1016/S0040-4020(01)89764-7

Source and publish data:

Tetrahedron p. 1963 - 1974 (1990)

Update date:2022-08-17

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Authors:

Agarwal, Seema

Tiwari Tiwari

Sharma Sharma

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Article abstract of DOI:10.1016/S0040-4020(01)89764-7

Based on the experimental data, a definite mechanism for the oxidation of primary and secondary alcohols with PCC and two newly synthesized Cr(VI) reagents has been proposed. The reaction has been shown to be a series reaction rather than a simple one step reaction as reported in the literature. The mechanism proposed has been exemplified by taking 2-pentanol as an example. The kinetic isotope studies have also been performed.

Full text of DOI:10.1016/S0040-4020(01)89764-7

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