Chemistry Letters p. 2303 - 2306 (1992)
Update date:2022-08-10
Topics:
Funabiki, Takuzo
Kashiba, Koji
Toyoda, Takehiro
Yoshida, Satohiro
Linear and branched alkanes are monooxygenated with O2 in nonheme iron complex/hydroquinone systems.Selectivity to form either alcohols or carbonyl compounds was controlled by the pyridine concentration.Reactivity of dfferent types of C-H bonds was affected by the substituents of hydroquinones, suggesting that hydroquinones are located in the vicinity of an active center in the product formation step.
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