Catalysis Communications p. 32 - 36 (2013)
Update date:2022-08-29
Topics:
Shul'pin, Georgiy B.
Kirillova, Marina V.
Shul'pina, Lidia S.
Pombeiro, Armando J.L.
Karslyan, Eduard E.
Kozlov, Yuriy N.
Ferrocene in an unexpected emploi: alkanes can be efficiently oxygenated by H2O2 in the presence of catalytic amounts of this well-known organometallic compound in combination with pyrazine-2-carboxylic acid or 2,2′-bipyridine. Saturated hydrocarbons, RH, are also transformed into carboxylic acids, RCOOH, when reacted with the ferrocene/CO/S 2O82 -/H2O system in acetonitrile solution.
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