Tetrahedron Letters p. 5139 - 5142 (1986)
Update date:2022-08-11
Topics:
Ballistreri, Francesco P.
Failla, Salvatore
Tomaselli, Gaetano A.
Curci, Ruggero
Mercuric acetate promoted oxidation of diaryl-, dialkyl-, and aralkylalkynes with (HMPA)MoO(O2)2 in 1,2-dichloroethane affords the corresponding α-diketones in good yields.Likewise, terminal alkynes can be converted into α-ketoaldehydes in excellent yields by using the same oxidizing system.
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