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Nickel(0)-catalyzed couplings of vinyl- alanes and -zirconocenes with chloromethylated heteroaromatics: A route to E-allylated heterocycles

DOI: 10.1016/S0040-4020(98)00342-1

Source and publish data:

Tetrahedron p. 6999 - 7012 (1998)

Update date:2022-08-28

Topics:

Authors:

Lipshutz, Bruce H.Lipshutz, Bruce H.

Kim, Sung-KyuKim, Sung-Kyu

Mollard, PaulMollard, Paul

Blomgren, Peter A.Blomgren, Peter A.

Stevens, Kirk L.Stevens, Kirk L.

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Article abstract of DOI:10.1016/S0040-4020(98)00342-1

Treatment of selected chloromethylated heteroaromatics, including pyridines, thiophenes, and furans, with vinyl alanes or vinyl zirconocenes in the presence of Ni(O) results in E-allylated products in good yields.

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Full text of DOI:10.1016/S0040-4020(98)00342-1

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