Journal of the American Chemical Society p. 6339 - 6348 (1990)
Update date:2022-09-26
Topics: Asymmetric synthesis Diastereoselectivity Column chromatography NMR spectroscopy Allylation Enantioselectivity Enantiomeric excess (ee) Optical rotation Workup Stereochemical Control Chiral Auxiliary Boronate ester Diastereomeric ratio (dr)
Roush, William R.
Ando, Kaori
Powers, Daniel B.
Palkowitz, Alan D.
Halterman, Ronald L.
Diisopropyl tartrate modified (E)- and (Z)-crotylboronates 2 and 3 are easily prepared with very high isomeric purity (≥98% E for 2; ≥99% Z for 3) via the metalation of (E)- and (Z)-2-butene with n-BuLi and KOtBu in THF followed by treatment of the (E)- a
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