PALLADIUM-CATALYZED CARBONYLATION OF PROPARGYLIC CARBONATES: PREPARATION OF 2,3- AND 2,4-DIENYL CARBOXYLATES

DOI: 10.1016/S0040-4039(00)84086-1

Source and publish data:

Tetrahedron Letters p. 731 - 734 (1986)

Update date:2022-09-26

Topics:

Authors:

Tsuji, Jiro

Sugiura, Teruo

Minami, Ichiro

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Article abstract of DOI:10.1016/S0040-4039(00)84086-1

Propargylic carbonates are converted to 2,3-dienyl carboxylates by the palladium-catalyzed decarboxylation-carbonylation in alcohol under mild conditions.In ether, 2,4-dienyl carboxylates are obtained.

Full text of DOI:10.1016/S0040-4039(00)84086-1

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