
Journal of the Chemical Society. Chemical communications p. 929 - 930 (1988)
Update date:2022-08-11
Topics:
Laurent, Pascale
Sabo-Etienne, Sylviane
Larsonneur, Anne-Marie
Abbayes, Herve des
Reaction of <(CO)4Fe(CO2R)>(1-) (1) (R = Me or But) with BrCH2CO2Me produces stable complexes <(CO)4Fe(CH2CO2Me)(CO2R)> (3) which thermally decompose to yield Fe(CO)5 and malonic esters under a CO atmosphere; these reactions provide the first demonstration of possible key steps in the catalytic cycle of the carbonylation of reactive halides into esters with Fe(CO)5 and an alkoxide anion.
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