Tetrahedron Letters p. 8211 - 8214 (1997)
Update date:2022-08-11
Topics:
Chen, Da-Wei
Takai, Kazuhiko
Ochiai, Masahito
Reported is the reactivity umpolung of diaryliodonium salts mediated by anhydrous chromium dichloride in the presence of a NiCl2 catalyst, which involves generation of an arylchromium(III) species, followed by the nucleophilic addition to aldehydes yielding benzyl alcohols.
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