EFFICIENT OLEFIN OXYGENATION WITH TETRAHYDROBORATE AND DIOXYGEN CATALYZED BY A RHODIUM PORPHYRIN COMPLEX

DOI: 10.1016/S0040-4039(00)86398-4

Source and publish data:

Tetrahedron Letters p. 1183 - 1186 (1983)

Update date:2022-08-16

Topics:

Authors:

Aoyama, Yasuhiro

Watanabe, Takamichi

Onda, Hiroyuki

Ogoshi, Hisanobu

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Article abstract of DOI:10.1016/S0040-4039(00)86398-4

Octaethylporphyrinatorhodium(III) shows an excellent catalytic activity in the oxygenation of simple olefins with tetrahydroborate and dioxygen in tetrahydrofuran to give alcohols via an anti-Markownikoff addition.

Full text of DOI:10.1016/S0040-4039(00)86398-4

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