Journal of Organic Chemistry p. 948 - 949 (1987)
Update date:2022-08-28
Topics:
Kira, Mitsuo
Sato, Kazuhiko
Sakurai, Hideki
Bis(diolato)hydridosilicates, derived from trichlorosilane and catechol or 2,2'-dihydroxybiphenyl in THF, can reduce aldehydes and ketones without any catalyst in very high yield.Chemo- and stereoselectivity as well as the structure and reactivity relatio
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