Nature of the Reactive Intermediates from the Iron-Induced Activation of Hydrogen Peroxide: Agents for the Ketonization of Methylenic Carbons, the Monooxygenation of Hydrocarbons, and the Dioxygenation of Arylolefins

Article abstract of DOI:10.1021/ja00035a043

The reaction efficiencies and product selectivities for a group of ML/HOOH/substrate/solvent systems have been evaluated.The catalysts include Fe(II)(PA)2, Fe(II)(DPA)2^2-, Fe(III)Cl3, (ClO4)2,