Tetrahedron Letters p. 4059 - 4060 (1989)
Update date:2022-08-22
Topics:
Anderson, David R.
Eley, Claudia N.
A Norrish type-II reaction is proposed for the photorearrangement of allyl diphenyl phosphate to ortho-allylphenyl phenylphosphate.In contrast to the type-II mechanism in carbonyl compounds, the reaction is postulated to proceed through a fivemembered transition state to produce a phosphoranyl 1,3-biradical which subsequently rearranges to the observed product.
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