Journal of Organic Chemistry p. 6937 - 6941 (1992)
Update date:2022-08-11
Topics:
Ito, Sotaro
Mitarai, Akira
Hikino, Kenji
Hirama, Mutsumi
Sasaki, Kazuo
The purpose of this work was to reveal the identity of the deactivation reaction involved in the Fenton's oxidation of aromatic compounds.The effect of reaction conditions on the yield of phenol in the oxidation of benzene was systematically studied.The maximum yield of phenol (93 percent based on H2O2 added) was obtained at low concentrations of both phenol formed and Fe(II) ion added.The predominant deactivation reaction of hydroxyl radicals in the Fenton's oxidation was found to be the reaction of hydroxyl radical with phenol to give phenoxy radical, followed by the reduction of phenoxy radical with Fe(II) ion to regenerate the phenol molecule.
View More
Valiant Fine Chemicals Co., Ltd.
Contact:+86 535 6101878/6374484
Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
Beijing Merson Pharmaceutical Co., Ltd
Contact:0086-10-80484934 0086-10-80484574/
Address:2nd Floor , No. 2 Building , No. 14 Houshayu Duan, Jingmi Road ,Shunyi District , Beijing 101318, P.R.China
Contact:+86-531-58668191 58668193 58668196 58661173
Address:No 55,Beixiaoxinzhuang West Street,Jinan City, Shandong Province
Quhua Zhongxing Refrigeration Technology Co.,Ltd.
Contact:+86-5708886618
Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
Liaoning Yufeng Chemical Co.,Ltd.
Contact:86-0419-3418888
Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
Doi:10.1063/1.441722
(1981)Doi:10.1016/j.saa.2007.07.059
(2008)Doi:10.1039/b606420e
(2006)Doi:10.1016/S0022-328X(00)93234-0
(1977)Doi:10.1016/j.bmcl.2014.09.066
(2014)Doi:10.1007/BF00766472
(1990)
