A Straightforward Synthesis of Allyl Amines from α-Amino Acids without Racemization

DOI: 10.1246/cl.1987.2085

Source and publish data:

Chemistry Letters p. 2085 - 2088 (1987)

Update date:2022-08-11

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Authors:

Moriwake, Toshio

Hamano, Shin-ichi

Saito, Seiki

Torii, Sigeru

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Article abstract of DOI:10.1246/cl.1987.2085

An extremely simple and practical synthesis of allyl amine derivatives from α-amino acids has been developed involving aldehyde olefination pathway with AlMe3-Zn-CH2I2 reagent which has proven to be crucial for preservation of stereochemical integrity.

Full text of DOI:10.1246/cl.1987.2085

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