Synthesis of 12-KETE and its 8,9-trans-isomer

DOI: 10.1016/S0040-4039(00)73109-1

Source and publish data:

Tetrahedron Letters p. 4051 - 4054 (1994)

Update date:2022-08-12

Topics:

Authors:

Wang Wang

Wang, Steven S.

Rokach Rokach

Rokach, Joshua

Powell Powell

Powell, William S.

Dekle Dekle

Dekle, Catherine

Feinmark

Feinmark, Steven J.

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Article abstract of DOI:10.1016/S0040-4039(00)73109-1

The first total synthesis of the highly unstable biological mediator 12-ketoeicosatetraenoic acid (12-KETE) 3 and its 8,9-trans-isomer 20 is presented. The strategy focusses on the stable precursor dithiane 13 and its conversion to 3 and 20. Biochemical e

Full text of DOI:10.1016/S0040-4039(00)73109-1

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