Tetrahedron Letters p. 4051 - 4054 (1994)
Update date:2022-08-12
Topics:
Wang
Wang, Steven S.
Rokach
Rokach, Joshua
Powell
Powell, William S.
Dekle
Dekle, Catherine
Feinmark
Feinmark, Steven J.
The first total synthesis of the highly unstable biological mediator 12-ketoeicosatetraenoic acid (12-KETE) 3 and its 8,9-trans-isomer 20 is presented. The strategy focusses on the stable precursor dithiane 13 and its conversion to 3 and 20. Biochemical e
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