A VERY ENANTIOSELECTIVE PHOTODECONJUGATION OF α,β-UNSATURATED ESTERS

DOI: 10.1016/S0040-4039(00)96635-8

Source and publish data:

Tetrahedron Letters p. 4825 - 4828 (1987)

Update date:2022-08-15

Topics: Catalyst Enantioselective Stereochemistry Enantiomeric excess Chiral Resolution UV-Vis Spectroscopy Photoisomerization Chirality Quantum Yield α,β-unsaturated esters

Authors:

Piva, Olivier

Henin, Francoise

Muzart, Jacques

Pete, Jean-Pierre

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Article abstract of DOI:10.1016/S0040-4039(00)96635-8

An enantiomer excess up to 70 percent can be obtained in the photodeconjugation of conjugated esters in the presence of (1R, 2S) 1-phenyl, 2-isopropylamino-propanol.

Full text of DOI:10.1016/S0040-4039(00)96635-8

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Product name:3-Pentenoic acid, 2,4-dimethyl-, phenylmethyl ester, (R)-

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