SELECTIVE SYNTHESIS OF (E)-CROTYLSILANES BY REACTION OF CROTYLMAGNESIUM BROMIDE WITH HYDROSILANES IN THE PRESENCE OF DICHLORONIKKEL(II)

DOI: 10.1016/S0040-4039(01)80196-9

Source and publish data:

Tetrahedron Letters p. 1499 - 1500 (1984)

Update date:2022-08-11

Topics:

Authors:

Hayashi, Tamio

Kabeta, Keiji

Kumada, Makoto

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Article abstract of DOI:10.1016/S0040-4039(01)80196-9

Dichloro<1,1'-bis(diphenylphosphino)ferrocene>nickel(II) was found to be an effective catalyst for the reaction of crotylmagnesium bromide with hydrosilanes to give (E)-crotyl-silanes selectively.

Full text of DOI:10.1016/S0040-4039(01)80196-9

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