Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 435 - 438 (1991)
Update date:2022-08-11
Topics:
Kliger, G. A.
Lesik, O. A.
Mikaya, A. I.
Marchevskaya, E. V.
Zaikin, V. G.
et al.
N-Alkylpiperidines with alkyl fragment length from C1 to C15 were synthesized by the reaction of CO + H2 + piperidine.The molecular mass distribution of the N-alkylpiperidines has two different distribution parameters α.Thus, α = 0.45 +/- 0.03 for C1-C5 alkyl fragments, while α = 0.65 +/- 0.02 for C6-C15.Piperidine was found to act as modifier reagent and chemical trap for the intermediates in the synthesis reaction.
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