Enzymatic alcoholysis of alkoxymethyl alkanoates: A possible approach for the kinetic resolution of tertiary alcohols

DOI: 10.1016/S0040-4039(98)01840-1

Source and publish data:

Tetrahedron Letters p. 8345 - 8348 (1998)

Update date:2022-08-11

Topics:

Authors:

Franssen, Maurice C.R.

Goetheer, Earl L.V.

Jongejan, Hugo

De Groot, Aede

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Article abstract of DOI:10.1016/S0040-4039(98)01840-1

The pivaloyloxymethyl and butanoyloxymethyl derivatives of tert-butanol and linalool (1.4) are readily accepted by hydrolases. Linalool derivative 4b is alcoholysed stereoselectively by Candida rugosa lipase (E=9.7).

Full text of DOI:10.1016/S0040-4039(98)01840-1

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