Nitrogen ligand complexes of metal chlorides as effective catalysts for the highly regio- and chemoselective silylation of hydroxyl groups with hexamethyldisilazane (HMDS) at room temperature

Article abstract of DOI:10.1080/00397919708004140

Zn(bipy)₃Cl₂, Fe(bipy)Cl₃, and Fe(tpp)Cl are effective catalysts for silylation of hydroxy groups with HMDS at room temperature in dry CH₃CN. High selectivity is observed between primary and secondary hydroxy fu

Full text of DOI:10.1080/00397919708004140

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Synthetic Communications: An
International Journal for Rapid
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Organic Chemistry
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Nitrogen Ligand Complexes of
Metal Chlorides as Effective
Catalysts for the Highly Regio-
and Chemoselective Silylation
of Hydroxyl Groups with
Hexamethyldisilazane (HMDS)
at Room Temperature
H. Firouzabadi a , A. R. Sardarian a , Z. Khayat a , B.
Karimi a & S. Tangestaninejad a
a Chemistry Department , Shiraz University , Shiraz,
71454, Iran
Published online: 22 Aug 2006.
To cite this article: H. Firouzabadi , A. R. Sardarian , Z. Khayat , B. Karimi & S.
Tangestaninejad (1997) Nitrogen Ligand Complexes of Metal Chlorides as Effective
Catalysts for the Highly Regio- and Chemoselective Silylation of Hydroxyl Groups with
Hexamethyldisilazane (HMDS) at Room Temperature, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 27:15,
2709-2719, DOI: 10.1080/00397919708004140
To link to this article: http://dx.doi.org/10.1080/00397919708004140
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