Chemistry of Heterocyclic Compounds p. 548 - 552 (1995)
Update date:2022-08-28
Topics:
Gubina, T. I.
Labunskaya, V. I.
Kornienko, G. K.
Borodina, L. A.
Kharchenko, V. G.
The kinetics of hydrolysis of 2,5-dimethylfuran and its recyclization into the corresponding thiophene were investigated in water-alcohol medium in 95, 80, and 50percent ethyl alcohol in the presence of HCl.It was found that the rates of these reactions are a function of both the initial concentration of the acid component and the concentration of water in the alcohol.The rate of hydrolysis is a function of the dilution of the alcohol to a greater degree than the rate of recyclization.
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