Tetrahedron p. 577 - 583 (1987)
Update date:2022-08-11
Topics:
Wermeckes, Bernd
Beck, Fritz
Schulz, Harry
The anodic oxidation of tetragydrofuran in acid aqueous electrolytes has been investigated in detail.Selective oxidation to 2-hydroxy tetrahydrofuran has been found to proceed.Under optimum conditions (smooth platinum, high current densities, 200 - 400 mA/cm2, 1 - 6 M THF, 1 M H2SO4, 35 deg C, quasi divided cells), the product was obtained in batch type laboratory scale (60percent of 2 F/mol conversion) with 70percent current efficiency and 95percent selectivity.Only traces of butyrolactone and succinic acid, the dominating products in the case of PbO2 anodes, were found.Oxygen is the main side product.
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