Hydrogenation of Arenes by the RhCl3-Aliquat 336 Catalyst. 4. Hydrogen-Deuterium Exchange and Other Mechanistic Features

DOI: 10.1021/jo00389a030

Source and publish data:

Journal of Organic Chemistry p. 2804 - 2813 (1987)

Update date:2022-08-17

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Authors:

Blum, Jochanan

Amer, Ibrahim

Vollhardt, K. Peter C.

Shwartz, Helmut

Hoehne, Gerhard

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Article abstract of DOI:10.1021/jo00389a030

The ion pair generated from RhCl3 and Aliquat 386 in an aqueos-organic two-phase medium was shown to catalyze the hydrogenation and deuteration of arenes at 30 deg C and 0.9 atm under apparently homogeneous conditions.The rate of the reductions was preced

Full text of DOI:10.1021/jo00389a030

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