The Selective Reduction of Benzene to Cyclohexene

DOI: 10.1039/c39820000379

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 379 - 380 (1982)

Update date:2022-08-25

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Authors:

Grundy, Stephen L.

Maitlis, Peter M.

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Article abstract of DOI:10.1039/c39820000379

Hydride attack on a dicationic η⁶-benzene complex gives the η⁴-cyclohexadiene, which with acid yields cyclohexene; in the presence of benzene the initial η⁶-benzene complex can be regenerated and a cycle established.

Full text of DOI:10.1039/c39820000379

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