Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 733 - 739 (1991)
Update date:2022-08-17
Topics:
Pogrebnoi, S. I.
Kal'yan, Yu. B.
Krimer, M. Z.
Smit, V. A.
A method has been developed for effecting rearrangements of allylacetoacetates to γ,δ-unsaturated ketones (Carroll rearrangement) and allylaryl ethers to the corresponding allylphenols (Claisen rearrangement) under conditions of adsorption on aluminum oxide and silica gel.The method provides a sharp reduction of the temperature of these reactions and improvement of their efficiency.
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